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Publication . Article . 2018

Germanium triazatetrabenzcorrole and germanium phthalocyanine: Synthesis, fluorescence and singlet oxygen generation

Xian-Fu Zhang; Xiaojie Sun;
Published: 21 Aug 2018 Journal: Journal of Porphyrins and Phthalocyanines, volume 22, pages 847-852 (issn: 1088-4246, eissn: 1099-1409, Copyright policy )
Publisher: World Scientific Pub Co Pte Lt
Abstract

The synthesis, fluorescence properties and singlet oxygen generation capability of germanium tetrabenzotriazacorrole (LGeTBC), germanium phthalocyanine (Cl[Formula: see text]GePc) and their derivatives are described. Measurements include UV-vis absorption spectra, fluorescence emission spectra, fluorescence quantum yields fluorescence lifetimes, and singlet delta oxygen quantum yields. LGeTBC and its derivatives exhibit quite different spectral and fluorescence properties from their phthalocyanine precursor. Both LGeTBC and Cl[Formula: see text]GePc show high singlet delta oxygen quantum yields and suitable fluorescence quantum yields, indicating that they can act as good singlet oxygen photosensitizers for photodynamic therapy.

Subjects by Vocabulary

Microsoft Academic Graph classification: Fluorescence Photodynamic therapy medicine.medical_treatment medicine Germanium chemistry.chemical_element chemistry Phthalocyanine chemistry.chemical_compound Photochemistry Corrole Singlet oxygen

Subjects

General Chemistry

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